Topic: NANOMAGNETISM: A NEW MATERIALS FRONTIER
Abstract
Nanocrystalline materials can possess bulk properties quite different from those commonly associated with conventional large-grained materials. Nanocomposites, a subset of nanocrystalline materials, in addition have been found to possess magnetic properties which are similar to, but different from, the properties of the individual constituents. This is true whether the constituent phases are molecular materials or polycrystalline solids. New magnetic phenomena, unusual property combinations, and both enhanced and diminished magnetic property values are just some of the changes observed in magnetic nanocomposites from conventional magnetic materials. Here, a description will be presented of some of these new properties and the exciting magnetic applications envisioned for them.Particular attention will be devoted to three world-leading activities in this area at NIST being pursued in the Magnetic Materials Group: the preparation of GMR spin valves having the world’s highest MR values with the smallest switching fields, the prediction and discovery of the "Enhanced Magnetocaloric Effect"in magnetic nanocomposites, and the dynamic observation of magnetic domains [using the magneto-optic imaging film (MOIF) technique] which are found to exist in these materials, including in magnetic exchange-biased films. These activities are assisting the rapid development of ultra-high density magnetic recording media,high temperature magnetic refrigerators, next-generation hard and soft ferromagnets, and controllable magnetic switches.
Curriculum Vitae
Robert D. Shull was born in Oak Ridge, Tennessee on November 12, 1946. After graduating from Lexington High School (Lexington, Massachusetts) in June 1964, he entered the Massachusetts Institute of Technology, receiving a Bachelor of Science degree in Metallurgy and Materials Science in June 1968 after presenting a thesis on the particle size effects of V2Zr on the critical fields (HC) and critical currents (IC) in superconducting Zr-V alloys. In the fall of 1968 he entered the University of Illinois at Urbana-Champaign to begin graduate work on the x-ray diffraction of AB3-type compounds. He served in the United States Army from February 1969 to February 1971 and recommenced his graduate program at the University of Illinois in September 1971. He received a Master of Science degree in Metallurgical Engineering in June 1973 and a Doctor of Philosophy degree in the same field in September 1976. During his latter graduate work he investigated the magnetic properties of many alloy systems under the direction of Professor Paul Beck, concentrating on order-disorder effects and properties of magnetically dilute systems. He was the discoverer of spin-glass and time-dependent behavior in Fe-Cr and Fe-Al alloys as well as the "reversed Curie temperature" phenomenon in Fe70Al30. From January 1976 to November 1979 Dr. Shull was awarded a postdoctoral fellowship at the California Institute of Technology to work with Professor Pol Duwez in the study of amorphous metals. During this period he used a microcalorimeter of his design (which allowed the measurement of very small mass samples down to 4.2 K) to show the existence of enhanced phonon modes at low frequencies in several early transition metal + late transition metal metallic glasses.
From November 1979 to the present Dr. Shull has been a member of the staff of the Metallurgy Division at the National Institute of Standards and Technology (NIST) located in Gaithersburg, Maryland. Initially, he set up the rapid solidification facilities which were used in the discovery of "quasicrystals" at this institution and was one of the first to show the power of small angle neutron scattering (SANS) in the characterization of amorphous metals. By means of differential scanning calorimetry (DTA), x-ray and neutron diffraction, and both optical and electron microscopy he was successful at clarifying the equilibrium phase diagram of the titanium-rich end of the Ti-Al system; and recently, Mössbauer measurements he conducted on nanocomposites of Ag + Fe3O4 have shown the existence of a very surprising grain size (and magnetic) transition in these sputtered thin film materials at a composition of only 5 wt % Ag. While working at NIST Dr. Shull was also part of the collaboration that prepared the first thin films of a high TC superconductor by the laser ablation process (now the method of choice of US industry for making thin films of these materials) and pioneered the magnetic-field-modulated microwave-absorption (MAMMA) measurement technique for very high sensitivity detection of superconducting transitions, was part of the effort that made the first direct observation of the atoms in high TC materials by field ion microscopy (FIM), and performed the low temperature magnetization measurements which first explained the novel "attractable levitation" effect found by others in some high TC superconducting oxide composites. International attention was particularly directed to Dr. Shull for his prediction and verification of the "Enhanced Magnetocaloric Effect" in nanocomposite materials, a finding which may have important ramifications in the field of magnetic refrigeration. (A 2004 publication of his on the huge effects of dopant additions to Gd5Ge2Si2 has even caused a re-evaluation in the refrigeration industry on how to properly compare magnetic refrigerants.) His surprising discovery that the remagnetization behavior in exchange-biased thin films proceeds by completely different processes when remagnetizing in opposite directions has caused the international magnetics community to revisit this area as it may have significant ramifications in the magnetic devices industry. And his discovery two years ago of a "Spin Density Wave” in a material (FeAl) with ferromagnetically interacting spins finally ends a 40-year old search by the magnetics community for such a theoretically predicted entity.
Dr. Shull has authored and co-authored over 150 publications, edited 5 books and 6 special scientific journal issues, received 2 patents, and presented over 275 talks (220 invited) at professional meetings in the areas of magnetism, superconductivity, phase equilibria, rapid solidification, and nanocomposites. One of these papers appeared on the cover of Science magazine (Jan. 8, 1988) and another [Phys. Rev. B36, No. 7 (1987) 4036] received an award for the “Best Paper of the Year” at the Applied Physics Laboratory of JHU. For the local ASM chapter he has taught courses on Rapid Solidification and on the Magnetic Properties of High TC Superconductors, and gave the keynote speech on Magnetic Nanocomposite Refrigerants at its November, 1994 Chapter meeting. In 1991 he was also the keynote speaker at the Washington/Baltimore Regional Meeting of the Materials Research Society. Dr. Shull has also organized 25 symposia and workshops on nanometer-scale materials, high TC superconductors, thermal analysis, and sol gels, and is an Associate Editor for the J. of NanoStructured Materials and also for the J. of Nanoparticle Research. He is a member of the International Committee on Nanostructured Materials (ICNM), elected as Secretary/Treasurer in 1992 and 1994, as Vice-Chairman in 1996 and as Chairman from 1999-2001. He was also the Organizer of the Third International Conference on Nanostructured Materials (NANO'96) in 1996, and of the First IEEE Nanotechnology Council Conference on Nanotechnology in 2001. Dr. Shull is also a member of the OSTP Nanoscale Science, Engineering, and Technology (NSET) Subcomittee (and its former entity, the Interagency Working Group on Nanotechnology, IWGN), the group which drafted the original National Nanotechnology Initiative (NNI) in 2001. Dr. Shull has been awarded three “NIST Director’s Innovation Awards”, one NIST Director’s Competence Award, the NIST EEO/Diversity Award, and the Outstanding Service Award by the NIST Chapter of Sigma Xi; he is presently the Group Leader of the Magnetic Materials Group at NIST. Dr. Shull is also the son of Dr. Clifford G. Shull, the winner of the 1994 NOBEL PRIZE in PHYSICS.
Dr. Shull is a member of TMS, ASM, APS, IEEE, ASTM, and Sigma Xi. In TMS he is the Vice President (and a Past Division Chair of the Electronic, Magnetic, and Photonic Materials Division). Dr. Shull is also a Past President of the NIST Chapter of Sigma Xi, a chapter which was first awarded the “Certificate of Excellence” from the National Sigma Xi organization during his tenure. He has also been a “Senior Member” of IEEE since 2002.
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