人才信息库
矫义来
性 别 最高学历 博士研究生
职 称 研究员 专家类别  
部 门 沈阳材料科学国家研究中心/生物基材料与仿生构筑研究部
通讯地址 辽宁省沈阳市沈河区文化路72号,中国科学院金属研究所,生物基材料与仿生构筑研究部
邮政编码 110016 电子邮件 yljiao@imr.ac.cn
电 话 +86-24-23971936 传 真 +86-24-23971896
简历:

  2006.07 至 2010.12 中国科学院金属研究所 博士学位

  2011.01 至 2013.09 中国科学院金属研究所 助理研究员

  2013.09 至 2020.12 中国科学院金属研究所 副研究员

  2016.09 至 2017.09 英国卡迪夫大学催化研究中心访问学者(合作者:Graham Hutichings)

  2016.09 至 2017.09 英国曼彻斯特大学化工系访问学者(合作者:Xiaolei Fan)

  2018.12 至今 沈阳材料科学国家研究中心 结构化催化材料PI

  2020.12 至今 中国科学院金属研究所 研究员

研究领域:
  1. 结构化催化剂构筑及其构效关系研究

  2. 等级孔沸石合成及其在催化、吸附与分离领域的应用

 

承担科研项目情况:

  作为项目负责人主持完成科技部“863”项目子课题2项、辽宁省自然科学基金面上项目、及中石油和航天五院等课题6项。作为项目主持在研国家自然科学基金面上项目“微波耦合结构化催化剂强化气固相催化反应机理(22078348)”、国家重点研发计划政府间国际科技创新合作重点专项“结构化沸石催化材料构筑及其在绿色溶剂合成中的应用(2019YFE0123200)”。参与完成UK EPSRC (No. EP/R000670/1)项目、参与在研European Union's Horizon 2020 grant (No. 872102)项目。主持项目累计科研经费1000余万元。

  

主要研究方向及特色

  矫义来紧扣“结构化催化材料”这一化工过程强化领域国际新兴前沿,同步开展科学研究与应用开发,国际上首次提出“涂覆结合蒸汽相转晶”制备分子筛涂层共性新方法,突破了“涂覆技术”通适性差的局限性,高效、可控制备出全结晶分子筛涂层,并实现百吨级规模化制备;提出中空分子筛涂层设计理念,制备出不同硅铝比中空分子筛涂层,澄清中空分子筛强化传质机理,制备出目前性能最优异的甲醇制丙烯催化剂并成功进行了吨级工业中试;提出中空分子筛涂层限域锚定活性金属策略,显著提高金属活性组分抗烧结、抗流失性能,实现二氧化碳加氢制甲烷热力学平衡转化,通过长周期考评,具备工业化应用潜质。近5年,以第一作者/通讯作者发表SCI论文20余篇(其中1区top期刊7篇,1区期刊6篇),如Angew. Chem. Int. Edit.(2020, top,IF=12.959)、Green Chem.(2020, top, IF=9.480)、AIChE J.(2020/2021,top, IF=3.519, 化工三大期刊之首)、Chem. Eng. J.(2017, top, IF=10.652, ESI高被引),J. Catal.(2015, top,IF=7.888)等。受邀撰写分子筛绿色合成专著一章(Elsevier,2020) ,专门介绍其在结构化分子筛构筑方面的研究成果。授权中国发明专利14项;申请国际发明专利2项,另有7项中国发明专利在实审之中。为中科大研究生讲授学位课《化工过程强化》;2020年获得中科大教师资格证书。

代表性成果简介

  ZSM-5型沸石由于其微孔结构和可调变的硅铝比,作为一种具有择形性的固体酸催化剂,在石油裂解、石化产品精制方面发挥着至关重要的作用。如何提高反应物对沸石酸性位的可接触性进而提高其催化性能,始终是近几十年以来沸石催化剂领域的研究重点,中空化则是实现这一目标的一条重要途径。拓扑结构重构——仅含四配位骨架铝的ZSM-5沸石母相(正交晶系)在有机胺中经溶解、再结晶形成中空ZSM-5沸石,是现有制备中空ZSM-5沸石的基本策略。沸石母相中的四配位铝结构对其溶解有着显著的抑制作用,使该策略只适用于制备硅铝比高于40的中空ZSM-5沸石。合成更低硅铝比的中空ZSM-5型沸石,使低硅铝比ZSM-5沸石的催化性能得到显著提高,仍是一个具有挑战性的课题。

  为打破四配位骨架铝结构对ZSM-5沸石母相溶解的抑制,矫义来提出了“晶型与拓扑结构同时重构”合成低硅铝比中空ZSM-5沸石催化剂的全新策略。该策略通过沸石前躯体的快速老化一步合成非四配位骨架铝的ZSM-5沸石母相(单斜晶系),再利用溶解、再结晶将非四配位骨架铝转化为四配位骨架铝,从而制备出硅铝比低至16的中空ZSM-5型沸石(正交晶系)。研究发现,非四配位骨架铝单斜晶系沸石母相较之于四配位骨架铝正交晶系沸石母相更容易在低浓度有机胺中溶解,是获得低硅铝比中空ZSM-5型沸石催化剂的基础。催化活性实验表明,硅铝比16的中空ZSM-5型沸石在碳氢化合物裂解中,尤其是在大分子碳氢化合物裂解中表现出高活性、高稳定性和高丙烯选择性的显著优势。脉冲场梯度核磁共振(PFG-NMR)表征结果则表明,低硅铝比中空ZSM-5型沸石所具有的优异催化性能来源于低硅铝比沸石中的高酸性位密度和中空结构良好传质性能的协同作用。该研究成果在化学顶级期刊Angewandte Chemie International Edtion(2020, 59, 19478)在线刊登。中国科学院官方网站对这一发现的科学意义给予高度评价。更为重要的是,该策略还能用于制备高骨架钛含量中空钛硅分子筛(TS-1)和开放介孔结构的TS-1型钛硅分子筛的制备。相关研究成果在Catalysis Science & Technology (2018, 8, 2211)和Micropore and Mesopore Materials(2020,305,110397)上发表,并申请中国发明专利(CN 201910340331.2.)。

 

社会任职:
获奖及荣誉:

  1.中国科学院金属研究所优秀青年学者奖,中国科学院金属研究所,2014

  2.Outstanding Contribution in Reviewing,国际分子筛学会,2017

  3.沈阳市高层次人才“拔尖人才”,沈阳市人才工作办公室,2018

  4.RCE Outstanding Early Career Researcher Paper Award,英国皇家学会,2019

代表论著:

专著:

  1.Xiaolei Fan, Yilai Jiao. Sustainable Nanoscale Engineering (1st Edition): From Materials Design to Chemical Processing, Chapter 5 Porous Materials for Catalysis: Toward Sustainable Synthesis and Applications of Zeolites, Elsevier, 2020

发表论文:

  1.S. Abdulridha, R. Zhang, S. Xu, A. Tedstone, X. Ou, J. Gong, B. Mao, M. Frogley, C. Bawn, Z. Zhou, X. Zhang, S. Chansai, S.M. Holmes, C. Hardacre, A.A. Garforth, S. Yang, Y. Jiao*, X. Fan*, An efficient microwave-assisted chelation (MWAC) post-synthetic modification method to produce hierarchical Y zeolites, Microporous and Mesoporous Materials, 311 (2021) 110715. (一区, IF=4.551, 国际分子筛协会会刊)

  2.S. Abdulridha, Y. Jiao, S. Xu, R. Zhang, Z. Ren, A.A. Garforth, X. Fan, A Comparative Study on Mesoporous Y Zeolites Prepared by Hard-Templating and Post-Synthetic Treatment Methods, Applied Catalysis A: General, 612 (2021) 117986. (二区, IF=5.006)

  3.R. Zou, X. Dong, Y. Jiao, D'A. Carmine, W. Yan, X. Fan, Controllable Synthesis, Diffusion Study and Catalysis of Hierarchical Zeolites, Chemical Journal of Chinese Universities, 42 (2021) 74-100. (四区,IF=0.649)

  4.H. Chen, Y. Shao, Y. Mu, H. Xiang, R. Zhang, Y. Chang, C. Hardacre, C. Wattanakit, Y. Jiao*, X. Fan*, Structured silicalite-1 encapsulated Ni catalyst supported on SiC foam for dry reforming of methane, AIChE Journal, n/a (2020) e17126. (TOP, IF=3.519, 美国化工学会会志,化工三大期刊之首)

  5.Y. Jiao*, L. Forster, S. Xu, H. Chen, J. Han, X. Liu, Y. Zhou, J. Liu, J. Zhang, J. Yu, C. D'Agostino*, X. Fan*, Creation of Al-Enriched Mesoporous ZSM-5 Nanoboxes with High Catalytic Activity: Converting Tetrahedral Extra-Framework Al into Framework Sites by Post Treatment, Angewandte Chemie International Edition, n/a (2020). (TOP,IF=12.959)

  6.S. Abdulridha, J. Jiang, S. Xu, Z. Zhou, H. Liang, B. Mao, Y. Zhou, A.A. Garforth, Y. Jiao*, X. Fan*, Cellulose nanocrystals (CNCs) as hard templates for preparing mesoporous zeolite Y assemblies with high catalytic activity, Green Chemistry, 22 (2020) 5115-5122. (TOP, IF=9.480)

  7.R. Zhang, H. Chen, Y. Mu, S. Chansai, X. Ou, C. Hardacre, Y. Jiao*, X. Fan*, Structured Ni@NaA zeolite supported on silicon carbide foam catalysts for catalytic carbon dioxide methanation, AIChE Journal, n/a (2020) e17007. (TOP, IF=3.519, 美国化工学会会志,化工三大期刊之首)

  8.Xiaoxia Ou, Fotios Pilitsis, Ninghui Xu, Arthur Garforth, Jinsong Zhang, Yilai Jiao*, Xiaolei Fan*. On developing ferrisilicate catalysts supported on silicon carbide (SiC) foam catalysts for continuous catalytic wet peroxide oxidation (CWPO) reactions. Catalysis Today. 356 (2020)631-640. (TOP, IF=5.825)

  9.X. Ou, C. Wu, K. Shi, C. Hardacre, J. Zhang, Y. Jiao*, X. Fan*, Structured ZSM-5/SiC foam catalysts for bio-oils upgrading, Applied Catalysis A: General, 599 (2020) 117626. (二区, IF=5.006)

  10.X. Gao, Q. Ding, Y. Wu, Y. Jiao*, J. Zhang, X. Li, H. Li*, Kinetic study of esterification over structured ZSM-5-coated catalysts based on fluid flow situations in macrocellular foam materials, Reaction Chemistry & Engineering, 5 (2020) 485-494. (二区, IF=3.441,Back Cover)

  11.Y. Jiao*, A.-L. Adedigba, N.F. Dummer, J. Liu, Y. Zhou, Y. Guan, H. Shen, M. Perdjon, G.J. Hutchings*, The effect of T-atom ratio and TPAOH concentration on the pore structure and titanium position in MFI-Type titanosilicate during dissolution-recrystallization process, Microporous and Mesoporous Materials, 305 (2020) 110397. (一区, IF=4.551, 国际分子筛协会会刊)

  12.Y. Guan, H. Shen, X. Guo, B. Mao, Z. Yang, Y. Zhou, H. Liang, X. Fan*, Y. Jiao*, J. Zhang*, Structured hierarchical Mn-Co mixed oxides supported on silicalite-1 foam catalyst for catalytic combustion, Chinese Journal of Chemical Engineering, (2020). (三区,IF=2.627)

  13.R. Zhang, P. Zhong, H. Arandiyan, Y. Guan, J. Liu, N. Wang, Y. Jiao*, X. Fan*, Using ultrasound to improve the sequential post-synthesis modification method for making mesoporous Y zeolites, Frontiers of Chemical Science and Engineering, 14 (2020) 275-287. (二区,IF=3.552)

  14.R. Zhang, D. Raja, Y. Zhang, Y. Yan, A.A. Garforth, Y. Jiao*, X. Fan*, Sequential Microwave-Assisted Dealumination and Hydrothermal Alkaline Treatments of Y Zeolite for Preparing Hierarchical Mesoporous Zeolite Catalysts, Topics in Catalysis, 63(2020)340. (二区, IF=3.340)

  15.S. Xu, S. Chansai, S. Xu, C.E. Stere, Y. Jiao, S. Yang, C. Hardacre, X. Fan, CO Poisoning of Ru Catalysts in CO2 Hydrogenation under Thermal and Plasma Conditions: A Combined Kinetic and Diffuse Reflectance Infrared Fourier Transform Spectroscopy–Mass Spectrometry Study, ACS Catalysis, (2020) 12828-12840. (TOP, IF=12.35)

  16.H. Chen, Y. Mu, Y. Shao, S. Chansai, H. Xiang, Y. Jiao, C. Hardacre, X. Fan, Nonthermal plasma (NTP) activated metal–organic frameworks (MOFs) catalyst for catalytic CO2 hydrogenation, AIChE Journal, 66 (2020) e16853. (TOP, IF=3.519, 美国化工学会会志,化工三大期刊之首)

  17.L. Lan, Y. Shao, Y. Jiao, R. Zhang, C. Hardacre, X. Fan, Systematic study of H2 production from catalytic photoreforming of cellulose over Pt catalysts supported on TiO2, Chinese Journal of Chemical Engineering, (2020). (三区,IF=2.627)

  18.A. Ismaila, H. Chen, Y. Shao, S. Xu, Y. Jiao, X. Chen, X. Gao, X. Fan, Renewable hydrogen production from steam reforming of glycerol (SRG) over ceria-modified γ-alumina supported Ni catalyst, Chinese Journal of Chemical Engineering, (2020). (三区,IF=2.627)

  19.S. Xu, S. Chansai, Y. Shao, S. Xu, Y.-c. Wang, S. Haigh, Y. Mu, Y. Jiao, C.E. Stere, H. Chen, X. Fan, C. Hardacre, Mechanistic study of non-thermal plasma assisted CO2 hydrogenation over Ru supported on MgAl layered double hydroxide, Applied Catalysis B: Environmental, 268 (2020) 118752. (TOP, IF=16.683)

  20.H. Xiang, A. Ameen, J. Shang, Y. Jiao, P. Gorgojo, F.R. Siperstein, X. Fan, Synthesis and modification of moisture-stable coordination pillared-layer metal-organic framework (CPL-MOF) CPL-2 for ethylene/ethane separation, Microporous and Mesoporous Materials, 293 (2020) 109784. (一区, IF=4.551, 国际分子筛协会会刊)

  21.S. Abdulridha, Y. Jiao, S. Xu, R. Zhang, A.A. Garforth, X. Fan, Mesoporous Zeolitic Materials (MZMs) Derived From Zeolite Y Using a Microwave Method for Catalysis, Frontiers in chemistry, 8 (2020)482. (二区, IF=3.693)

  22.R. Vakili, R. Gholami, C.E. Stere, S. Chansai, H. Chen, S.M. Holmes, Y. Jiao, C. Hardacre, X. Fan, Plasma-assisted catalytic dry reforming of methane (DRM) over metal-organic frameworks (MOFs)-based catalysts, Applied Catalysis B: Environmental, 260 (2020) 118195. (TOP, IF=16.683)

  23.B. Fan, Z. Guo, X. Li, S. Li, P. Gao, X. Xiao, J. Wu, C. Shen, Y. Jiao, W. Hou, Electroactive barium titanate coated titanium scaffold improves osteogenesis and osseointegration with low-intensity pulsed ultrasound for large segmental bone defects, Bioactive Materials, 5 (2020) 1087-1101.(IF=8.724)

  24.Yilai Jiao*, Xiaoxia Ou, Jinsong Zhang, Xiaolei Fan*. Structured of ZSM-5 Coated SiC Foam Catalysts for Process Intensification in Catalytic Cracking of n-Hexane. Reaction Chemistry & Engineering, 4 (2019)427-435. (二区, IF=3.441, Invited submission for the Themed Collection of 2019 Emerging Investigators, and shortlist as RCE Outstanding Early Career Researcher Paper Award)

  25.Rongxin Zhang, Shaojun Xu, Duaa Raja, Nor Binti Khusni, Jinmin Liu, Jiaoyu Zhang, Samer Abdulridha, Huan Xiang, Songshan Jiang, Yanan Guan, Yilai Jiao*, Xiaolei Fan*. On the effect of mesoporosity of FAU Y zeolites in the liquid-phase catalysis. Microporous and Mesoporous Materials, 278 (2019) 297-306. (一区, IF=4.551, 国际分子筛协会会刊)

  26.Xiaoxia Ou, Fotios Pilitsis, Yilai Jiao, Yong Zhang, Shaojun Xu, Martin Jennings, Yi Yang, SF Rebecca Taylor, Arthur Garforth, Huiping Zhang, Christopher Hardacre, Ying Yan, Xiaolei Fan. Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO). Chemical Engineering Journal, 362 (2019)53-62. (TOP, IF=10.652)

  27.Renzheng Jiang, Yilai Jiao, Yingpeng Xie, Zhenming Yang, Jinsong Zhang. SiC foam based structured catalyst for process intensification in oxidative dehydrogenation of 1-butene to butadiene. Chemical Engineering and Processing-Process Intensification, 137 (2019) 108-115. (三区, IF=3.731)

  28.Kai Li, Yilai Jiao, Zhenming Yang, Jinsong Zhang. A comparative study of Ni/Al2O3-SiC foam catalysts and powder catalysts for liquid-phase hydrogenation of benzaldehyde. Journal of Material Science & Technology. 35(2019)159-167. (一区, IF=6.155)

  29.Huanhao Chen, Yibing Mu, Yan Shao, Sarayute Chansai, Shaojun Xu, Cristina E Stere, Huan Xiang, Rongxin Zhang, Yilai Jiao, Christopher Hardacre, Xiaolei Fan. Coupling non-thermal plasma with Ni catalysts supported on BETA zeolite for catalytic CO2 methanation. Catalysis Science & Technology, 9 (2019) 4135-4145. (二区, IF=5.726)

  30.Fengyu Hao, Cuicui Zhang, Lin Wu, Yong Gao, Yilai Jiao. Both silicalite-1/SiC foam and ZSM-5/SiC foam may serve as novel bone replacement materials. Annals of translational medicine, 7 (2019): 1-9. (二区, IF=3.297)

  31.Yilai Jiao, Shaojun Xu, Chunhai Jiang, Michal Perdjon, Xiaolei Fan, Jinsong Zhang. MFI zeolite coating with intrazeolitic aluminum (acidic) gradient supported on SiC foams to improve the methanol-to-propylene (MTP) reaction. Applied Catalysis A: General. 559 (2018) 1-9. (二区, IF=5.006)

  32.Yilai Jiao, Abdul-Lateef Adedigba, Qian He, Peter Miedziak, Gemma Brett, Nicholas F Dummer, Micheal Perdjon, Jinmin Liu, Graham J Hutchings. Inter-connected and open pore hierarchical TS-1 with controlled framework titanium for catalytic cyclohexene epoxidation. Catalysis Science & Technology. 8 (2018) 2211-2217. (二区, IF=5.726)

  33.Zuwei Liao, Ting Xu, Yuntao Jiang, Binbo Jiang, Jingdai Wang, Yongrong Yang, Yilai Jiao, Zhenming Yang, Jinsong Zhang. Methanol to propylene over foam SiC supported ZSM-5 catalyst: Performance of multiple reaction-regeneration cycles. Industrial & Engineering Chemistry Research. 58(2018)27-33. (TOP, IF=3.573, 化工三大期刊)

  34.李恺, 矫义来, 杨振明, 张劲松. 制备方法对 Ni/Al2O3-SiC 泡沫结构催化剂 Ni 分布和苯甲醛加氢性能的影响. 材料研究学报. 32 (2018) 811-819

  35.姜仁政, 矫义来, 孙博, 杨晓丹, 杨振明, 张劲松. ZnFe2O4-α-Fe2O3/SiC 泡沫结构催化剂的制备和丁烯氧化脱氢性能. 材料研究学报. 32 (2018) 225-232

  36.姜仁政, 矫义来, 孙博, 杨晓丹, 杨振明, 张劲松. 铁酸锌泡沫结构催化剂床层高径比对1-丁烯氧化脱氢性能的影响. 南京工业大学学报(自然科学版). 40(2018)1-5

  37.Xiaoxia Ou, Shaojun Xu, Jason M. Warnett, Stuart M. Holmes, Amber Zaheer, Arthur A. Garforth, Mark A. Williams, Yilai Jiao*, Xiaolei Fan. Creating hierarchies promptly: Microwave-accelerated synthesis of ZSM-5 zeolites on macrocellular silicon carbide (SiC) foams. Chemical Engineering Journal, 312 (2017) 1–9. (TOP, IF=10.652, 化工三大期刊, 2018 Highly Cited Paper in the field of Engineering by the Web of Science)

  38.Yilai Jiao, Xiaolei Fan, Michal Perdjon, ZhenmingYang, Jinsong Zhang. Vapor-phase transport (VPT) modification of ZSM-5/SiC foam catalyst using TPAOH vapor to improve the methanol-to-propylene (MTP) reaction. Applied Catalysis A: General. 545 (2017) 104-112. (二区, IF=5.006)

  39.全泉, 矫义来, 曹洪娟, 吴琳. 超声作用下 2 种压电陶瓷多孔支架材料上成骨细胞的增殖与分化. 中国医科大学学报. 46 (2017) 869-873

  40.Yilai Jiao, Xiaodan Yang, Chunhai Jiang, Chong Tian, Zhenming Yang, Jinsong Zhang. Hierarchical ZSM-5/SiC nano-whisker/SiC foam composites: preparation and application in MTP reaction. Journal of catalysis, 332 (2015) 70–76.(一区,top,IF=7.723)

  41.Yong Li, Yilai Jiao, Xiaokang Li, Zheng Guo. Improving the osteointegration of Ti6Al4V by zeolite MFI coating. Biochemical and Biophysical Research Communications, 460 (2015) 151–156. (二区,IF=2.705)

  42.矫义来, 杨晓丹, 杨振明, 张劲松. 结构化纳米分子筛催化剂的甲醇制丙烯性能.第18届全国分子筛学术大会论文集(上). 2015

  43.杨振明, 田冲, 矫义来, 姜春海, 杨晓丹, 郝栋, 张劲松. 泡沫碳化硅的制备及应用. 化学反应工程与工艺, 29(2015)269-275

  44.Yilai Jiao, Chunhai Jiang, Zhenming Yang, Jinsong Zhang. Synthesis of highly accessible ZSM-5 coatings on SiC foam support for MTP reaction. Microporous and Mesoporous Materials, 181 (2013) 201–207.(二区,IF=3.615)

  45.Yilai Jiao, Chunhai Jiang, Zhenming Yang, Jinsong Zhang. Controllable synthesis of ZSM-5 coatings on SiC foam support for MTP application. Microporous and Mesoporous Materials, 162 (2012) 152–158. (一区, IF=4.551, 国际分子筛协会会刊)

  46.矫义来,杨振明,张劲松。在泡沫碳化硅载体上原位生长 silicalite-1 型沸石晶体。材料研究学报, 1(2010)25-32

  47.矫义来,杨振明,曹小明,田冲,苏党生,张劲松。在泡沫碳化硅载体上自转化合成 silicalite-1 型沸石晶体。23(2009)458-465 (封面)

  48.矫义来,杨振明,曹小明,田冲,高勇。泡沫碳化硅陶瓷表面原位合成Silicalite-1沸石的研究。稀有金属材料与工程。 38(2009)286-288

  49.韩亚苓, 矫义来, 李伟, 孙泰礼. Al2O3/SiC纳米复合陶瓷中SiC粉料的氧化现象. 沈阳工业大学学报. 29(2007)130-134

  50.矫义来,韩亚苓,王双,孙泰礼。ZrO2粉料在Al2O3-SiC纳米复合陶瓷中的作用. 27(2005)389-392

  51.王双, 孙泰礼, 韩亚苓, 矫义来. Al2O3/SiC纳米复相陶瓷断裂韧性的研究. 沈阳工业大学学报. 27(2005)148-150

  52.矫义来, 韩亚苓, 李伟, 孙泰礼. ZTA陶瓷材料的显微组织研究. 纳米材料与技术应用进展—第四届全国纳米材料会议论文集. 2005

授权专利:

  1.张劲松, 矫义来, 郝玉林, 李述军. 一种适合超声治疗的生物医用钛材料及其制备方法和应用. 申请号: ZL 201610715314.9. 批准时间: 2020.08.21.

  2.张劲松, 矫义来, 高勇, 杨振明, 杨晓丹, 高飞, 周华群, 张兆前, 董卫刚. 在泡沫碳化硅载体表面涂覆有ZSM-5分子筛涂层的复合材料的制备方法. 专利号: ZL201410766931.2. 批准时间: 2018.06.01.

  3.蒋斌波, 蒋云涛, 周冰洁, 廖祖维, 黄正梁, 王靖岱, 阳永荣, 矫义来, 孟嘉辉, 王中仁, 严丽霞, 许彩霞. 固定床反应器中结构化催化剂定点再生方法. 专利号: ZL201510123259.X. 批准时间: 2017.07.11.

  4.张劲松, 杨晓丹, 杨振明, 矫义来, 高勇. 一种用于乙炔氢氯化反应的改进结构催化剂及其制备方法. 专利号: ZL201310465171.7. 批准时间: 2016.01.13.

  5.张劲松, 矫义来, 杨振明. 一种结构化催化剂强化甲醇制取二甲醚的方法. 专利号: ZL201310401467.2. 批准时间: 2015.12.23.

  6.张劲松, 矫义来, 杨振明. 一种恢复泡沫碳化硅基结构化分子筛催化剂活性的方法. 专利号:ZL201310401519.6. 批准时间: 2015.09.16.

  7.张劲松, 矫义来, 杨振明. 一种多级孔结构纳米MFI型分子筛及其制备方法和应用. 专利号: ZL201310405420.3. 批准时间: 2015.08.12.

  8.张劲松, 矫义来, 杨振明. 一种ZSM-5/泡沫碳化硅结构化催化剂的改性方法. 专利号: ZL201310401489.9. 批准时间: 2015.06.24.

  9.张劲松, 矫义来, 杨振明. 一种多孔碳化硅载体表面梯度空隙分子筛涂层及其制备. 专利号: ZL201310164573.3. 批准时间: 2014.12.10.

  10.张劲松, 矫义来, 杨振明,田冲, 曹小明. 一种高丙烯产率甲醇制丙烯的方法. 专利号: ZL201010602946.7. 批准时间: 2014.10.22.

  11.张劲松, 杨振明, 矫义来, 田冲, 曹小明, 高勇, 杨晓丹. 一种泡沫碳化硅基结构化催化剂及在制备丁二烯中的应用. 专利号: ZL201310061265.8. 批准时间: 2014.08.27.

  12.张劲松, 矫义来, 杨振明. 基于泡沫碳化硅的超细分子筛催化材料及其制备. 专利号: ZL201110156980.0. 批准时间: 2014.06.11.

  13.张劲松, 杨振明, 矫义来,田冲,曹小明. 一种活性炭涂层/泡沫碳化硅结构化催化剂及其制备方法. 专利号: ZL2010306110.1. 批准时间: 2014.02.12.

  14.张劲松, 矫义来, 高勇, 徐兴祥, 杨振明, 张军旗. 一种医用多孔含钛材料表面分子筛涂层材料及其制备方法. 专利号: ZL201110210812.5. 批准时间: 2013.11.20.

申请专利:

  1.Fan, X.; Jiao, Y. A microwave-assisted chelation protocol to create mesoporosity in zeolites (Zeolite modification process and product thereof). Patent application WO 2020/053592 A1. The University of Manchester Intellectual Property UMIP?.

  2.张劲松, 高勇, 田冲, 杨振明, 杨晓丹, 矫义来. 一种中空泡沫材料及其制备方法和应用. 申请号: WO2018086522A1 申请时间: 2016.11.9.

  3.张劲松, 矫义来. 高骨架钛含量开放多级孔钛硅分子筛及其制备方法和应用. 申请号: CN 201910340331.2. 申请时间: 2019.04.25.

  4.张劲松, 矫义来, 管亚男, 田冲, 刘强. 一种结构化催化材料及在VOCs催化燃烧过程中的应用. 申请号: CN 201910340327.6. 申请时间: 2019.04.25.

  5.张劲松, 矫义来, 管亚男, 刘强. 一种憎水结构化催化材料及其制备方法与应用. 申请号: CN 201910341065.5. 申请时间: 2019.04.25.

  6.张劲松, 矫义来, 杨振明. 一种结构化催化剂上过氧化氢的生产方法. 申请号: CN 201910018128.8. 申请时间: 2019.01.09.

  7.张劲松, 矫义来, 郭兴, 杨生胜, 薛玉雄, 庄建宏. 一种晶振表面分子筛膜材料及其制备方法和应用. 申请号: CN 201810832274.5. 申请时间: 2018.07.26.

  8.张劲松, 高勇, 杨振明, 矫义来, 杨晓丹, 高飞, 周华群, 董卫刚, 张兆前. 用于天然气水蒸气重整制合成气反应过程的泡沫碳化硅结构化催化材料及其制备方法. 申请号: CN105728007A. 申请时间: 2016.07.06.

  9.张劲松, 杨晓丹, 杨振明, 矫义来, 高勇. 一种乙炔氢氯化反应结构催化剂及其制备方法. 申请号: CN103506147A. 申请时间: 2014.01.15.

 

 

 

个人网页: